Abstract
Iridium-catalyzed 1,3-hydrogen shift/chlorination of allylic alcohols.
Highlights
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We envisaged that a-chloroketones could be synthesized with complete regiocontrol from allylic alcohols through a 1,3-hydrogen shift/chlorination catalyzed by transition metals
We show here a short synthesis of 2-aminothiazoles (9–12) from allylic alcohols (2 f, 2 c, 2 o, and 2 e, respectively, Scheme 6)
Summary
Access to the published version may require subscription. N.B. We envisaged that a-chloroketones could be synthesized with complete regiocontrol from allylic alcohols through a 1,3-hydrogen shift/chlorination catalyzed by transition metals. Synthesis of a-functionalized ketones through a) enolization/enamine formation; b) transition-metal-catalyzed isomerization of allylic alcohols.
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