Abstract
AbstractHighly enantioselective allylic alkylation reactions of methyl 2‐(4‐nitrophenylsulfonyl)acetate were carried out in the presence of an iridium catalytic system. The subsequent transformations of the products including reductive desulfonylation and modified Julia olefination led to the allylic alkylation products of methyl acetate or methyl acrylate with good yields and high enantioselectivity.
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