Abstract
Evidence of double hydrogen-bond formation between dichloromethane and electron-donor molecules is given using IR spectroscopy. The analysis of IR spectra is based mainly on the intensity changes of the ν 1 and ν 6 CH-stretching vibration bands of dichloromethane and deuterated dichloromethane dissolved in several electron-donor solvents. Dimerisation of dichloromethane diluted in inert solvents was also observed.
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