Year-end Sale % OFF 
Abstract
By the method of IR spectroscopy the interaction of various π-complexes of transition metals with proton donors in liquid Xe solutions at 165–270 K have been studied. Perfluoro-tert.-butanol (PFB) and HCl were used as proton donors, since they are not associated in liquid Xe. Ferrocene and its alkyl derivatives form H-bonds of OH… π type with PFB with participation of π-electrons of the cyclopentadienyl ring. For carbonyl and nitrosyl complexes the new types of H-bonding MCO…HA and MNO…HA with the oxygen atoms of carbonyl and nitrosyl ligands have been found. It is shown that H-bond with the oxygen atom might be the first step in the reaction of proton transfer to the metal atom.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
