Abstract

• Heterobimetallic manganese tricarbonyl-ferrocene complex prepared. • Redox processes studied with cyclic voltammetry (CV). • Reversible redox wave at ferrocene but irreversible ones on manganese centre. • IR spectroelectrochemistry used to study interaction between two metal sites. Heterobimetallic manganese tricarbonyl-ferrocene complex studied with IR spectroelectrochemistry for CO release.

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