Abstract
We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast β process, commonly ascribed to caged molecular dynamics. Aside from the known variation of the structural α relaxation time and a modification of the excess wing with ion content, we also find a clear influence on the shallow loss minimum arising from the fast β relaxation. Within the framework of mode-coupling theory, the detected significant broadening of this minimum is in reasonable accord with the found variation of the α-relaxation dynamics. A correlation between α-relaxation rate and minimum position holds for all ion concentrations and temperatures, even below the critical temperature defined by mode-coupling theory.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
