Abstract
The values of ΔG0 at 25 °C were determined for the ionization, dimerization, and trimerization of tetra-n-butylammonium picrate (1) in benzene, chlorobenzene, and o-dichlorobenzene by a solvent extraction method. Corrections were applied for the presence of hydrates in the organic phase, in order to report ΔG0 values for the anhydrous solvents. In chlorobenzene, hexamers of 1 were also indicated in measurable concentrations. The various values of ΔG0 are related in a simple way to the bulk dielectric constant of the solvent.
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