Abstract
Conductances at 25°C were measured in the following systems: Potassium chlorate in water-methanol and in water-ethylene carbonate mixtures, and sodium-chlorate in some water-methanol mixtures. Both salts are poorly associated in water but addition of small amounts of methanol or of ethylene carbonate markedly increases and decreases respectively the association. These results, not explained on the basis of a continuum model, can be rationalized considering a specific solvation in connection with the structure of the solvent mixtures.
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