Abstract

A highly crystalline one-dimensional zirconium phosphate, (NH4)2[ZrF(PO4)(HPO4)] (ZrP-3), was facilely synthesized by the ionothermal method. The robust structure and rich hydrogen-bonded network make ZrP-3 an excellent proton conductor by having a proton conductivity higher than 10-2 S cm-1 at 90 °C and 95% RH. The remarkable stability makes ZrP-3 a promising solid electrolyte material for proton exchange membrane fuel cells.

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