Abstract

A method, involving the use of paper electrophoresis is described for the study of the equilibria in mixed ligand complex systems in solution. Plots of -log [methionine] against mobility were used to obtain information on the formation of mixed complexes and to calculate the stability constants. Metal (M)-methionine and M-nitrilotriacetate (NTA) binary equilibria were also studied since this is a prerequisite for the investigation of mixed complexes. The stability constants (log K) of the M-NTA-methionine complexes were found to be 6.02±0.03 and 4.92±0.01 for M=Al(III) and Th(IV), respectively, at μ = 0.1 mol/l and 35°C.

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