Abstract
AbstractIt is shown by ion cyclotron resonance measurements that ion/molecule reactions, leading to substitution or reduction product ions from chloro‐ and nitrobenzene with the title amines, are those between the molecular ions [RNH2]+ or [C6H5X]+˙ and their respective counterparts C6H5X or RNH2. The protonated reagent gas ions [RNH3]+ are not involved in these reactions. In the case of nitrobenzene, adduct ions [C6H5NO2·RNH3]+ do not decompose within the time scale of the measurements. The results obtained are compared with those found under chemical ionization conditions.
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