Abstract

The selective adsorption of trace Po IV complex ions by ionized monolayers of cationic soaps adsorbed at a 1 M HC1 solution/air interface was studied. The monolayers behave like two-dimensional ion-exchangers. An original device was set up to measure their surface potentials using two 241Am ionizing electrodes. The adsorption-distribution coefficient of the trace anions increased with the total surface potential of the ionized monolayer. It appears that a singly charged complex anion is adsorbed, PoC1 6H −, which penetrates behind the plane of the positively charged head-groups.

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