Abstract
AbstractThe field ionization mass spectrum of diethylamine on a 5 μm activated wire at 300 K yields surface product ions like protonated molecular ions and doubly charged ions as well as gas phase ions like parent minus CH3 group. Variations of the reaction rate as a function of the decomposition times in the range 10−11‐10−6 s for the elimination of a CH3 group are studied. The reaction rates are evaluated with the help of the retarding potential technique.
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