Ion-imprinted poly(2-acrylamido-2-methyl-1-propansulfonic acid)/modified silica composite hydrogel for selective and enhanced adsorption of Pb(II) ions

Abstract

AbstractIn this research, ion-imprinted poly(2-acrylamido-2-methyl-1-propansulfonic acid)/modified silica composite hydrogels were prepared using Pb(II) ions as template by in situ free-radical polymerization. The ability of the imprinted composite hydrogels to adsorb and remove Pb(II) ions from aqueous solutions was assessed using batch adsorption technique. The adsorption amount was pH-dependent, and the maximum adsorption capacity was observed at pH 5.0. The adsorption process could be well described by the Langmuir isotherm. The adsorption equilibrium was achieved within 15 min, and the kinetics of adsorption followed a pseudo-second-order rate equation. Thermodynamic parameters such as the Gibbs free energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS0) for the metal ion adsorption were estimated. Results suggested that the adsorption process was a spontaneous, exothermic process that had positive entropy. The Pb(II) ion-imprinted composite hydrogels exhibited extremely high selectivity coefficient, which ...