Abstract
AbstractCoordination of Ag(I) with the anion of a sulfanilamide (L) usually produces a non‐conducting compound of the composition AgL. However, with sulfamethoxypyrazine and sulfacetamide an ionic compound [AgL2]Ag is formed. Model substances demonstrate that the presence of one suitable donor atom (the deprotonated acidic N) results in the formation of ionic compounds of type [AgL2]Na and [AgL2]Ag. The presence of an aromatic NH2 group as the second donor group results in the formation of only one type, namely [AgL2]Ag. The silver compounds were studied by the use of conductivity, UV and IR measurements.
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