Abstract
The demand for cesium is expanding rapidly in light of its necessity in high-tech industries. Thus, technologies that can efficiently extract cesium from the sources are critically needed. Here, the metal-organic framework (MOF) membranes created from -Cl and -NH2 functionalized MIL-53 enabled highly selective transport of cesium ions. The angstrom-scale pore windows in these MOFs conduct Cs+ ions at high throughput, 2 orders of magnitude faster than other marginally larger ions. Ascribed to size sieving effects, MIL-53-NH2 containing 6.6 Å size channels realized an exceedingly high Cs+/Li+ selectivity up to ∼315. The rapid transport of Cs+ ions relative to other ions is greatly dependent on the precision of the angstrom-scale pores. Our work highlights the enormous potential of realizing high ion selectivity with MOFs and drives the further development of these materials in a variety of advanced separations.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
