Abstract
An ionic porous aromatic framework is developed as a self-degraded template to synthesize the magnetic heterostructure of γ-Fe2O3/WO3·0.5H2O. The Fe3O4 polyhedron was obtained with the two-phase method first and then reacted with sodium tungstate to form the γ-Fe2O3/WO3·0.5H2O hybrid nanostructure. Under the induction effect of the ionic porous network, the Fe3O4 phase transformed to the γ-Fe2O3 state and complexed with WO3·0.5H2O to form the n-n heterostructure with the n-type WO3·0.5H2O on the surface of n-type γ-Fe2O3. Based on a UV-Visible analysis, the magnetic photocatalyst was shown to have a suitable band gap for the catalytic degradation of organic pollutants. Under irradiation, the resulting γ-Fe2O3/WO3·0.5H2O sample exhibited a removal efficiency of 95% for RhB in 100 min. The charge transfer mechanism was also studied. After the degradation process, the dispersed powder can be easily separated from the suspension by applying an external magnetic field. The catalytic activity displayed no significant decrease after five recycles. The results present new insights for preparing a hybrid nanostructure photocatalyst and its potential application in harmful pollutant degradation.
Highlights
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations
The construction of a heterostructure catalyst with different semiconductor constituents has become more popular in recent years [1,2,3,4,5,6]
This combination can improve the efficiency of photocatalytic reaction activity by building an inner electric field to separate charge carriers
Summary
The construction of a heterostructure catalyst with different semiconductor constituents has become more popular in recent years [1,2,3,4,5,6]. This combination can improve the efficiency of photocatalytic reaction activity by building an inner electric field to separate charge carriers. For the purpose of separating photogenerated electron–hole pairs to improve the catalytic performance, several approaches have been developed in recent years, including surface modification with noble metals, special morphologies/phase control, and the formation of nanomaterial composites [18,19,20].
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
