Abstract
Several new ionic liquids were prepared from trialkylsulfonium bromides and AlCl3 or HCl. They include both Lewis basic and acidic combinations of Et3SBr with AlCl3, which are liquid at ambient temperatures. Density, molarity, conductivity, NMR, infrared, and electrochemical data are presented. The sulfonium cations are not hydrogen bonding, are unattacked by hydride, provide NMR windows in the aromatic regions, and offer different solubility prospects from ionic liquids derived from aromatic cations.Key words: ionic liquids, triethylsulfonium, haloaluminates, halohydrogenates, molarities, NMR, voltammetry, hydride.
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