Abstract
AbstractMagnesium batteries are promising candidates for post‐lithium energy storage systems due to their low cost, high volumetric energy density, and low risk of dendrite formation. This study reports a new magnesium ion conducting ionogel electrolyte based on a Metal‐Organic Framework (MOF) structure (UiO‐66) impregnated with an ionic liquid, magnesium bis[(trifluoromethyl)sulfonyl]imide in 1‐ethyl‐3‐methylimidazolium bis[(trifluoromethyl)sulfonyl]imide. Comparably high conductivity of 5.7×10−5 S cm−1 can be achieved at room temperature. By employing the prepared MOF‐ionogel electrolyte, a reversible quasi‐solid‐state magnesium battery (QSSMB) is reported. Surface analysis unveils the possible origin of the large overpotential of magnesium plating and stripping. The findings suggest that MOF‐based materials are a promising class of ionogel electrolyte templates for QSSMBs. The results on the magnesium anode will be useful to define optimization strategies for magnesium metal anodes in SSMBs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
