Ionic liquid-based molecular design for transparent, flexible, and fire-retardant triboelectric nanogenerator (TENG) for wearable energy solutions

Abstract

Transparent and flexible triboelectric nanogenerator (TENG) represent an efficient and invisible energy solution for generating eco-friendly electricity from mechanical human motion for wearable electronic devices and systems. In addition to boosting the output performance of TENG, the molecular design relying on non-flammable materials and anti-ignition invulnerability should be considered when designing TENG devices, to ensure the safety of personnel working under extreme temperature conditions. However, the requirement for non-flammability of conventional transparent triboelectric materials in wearable applications remains either unmet or almost unexamined to date. Here, we propose bi-continuous and flame-retarding epoxy-based ion-gel films that retain mechanical flexibility, optical transparency, and fast ionic polarization for high-performance and deformable TENG. It is found that our transparent and flexible TENG devices produce an output voltage and current as high as approximately 150 V and 45 μA, respectively, from an external mechanical stimulus while also retaining their fire retardancy and low flammability. This TENG is not flammable even after 20 s of trying, whereas conventional triboelectric materials were completely burned by the fire under the same conditions. Therefore, we propose that our synergistic design of triboelectric ion-gel films, including fire-retardant epoxy-based dual cation-incorporated ionic liquid, represents a significant step toward a high-performance, durable, and transparent wearable energy solution. A new type of ionic liquid-based molecular design for our TENG device structure containing dual-positive ions and forming the electrical double layer (EDL) due to the rapid movement of internal ions during friction. It was intended that the dual ILs including Li+ and EMIM+ positive ions can easily transport through the bi-continuous structure of fire-resistant polymer backbone upon the mechanical surface friction as depicted in the right image. • Ionic liquid-based molecular design for high-performance and mechanically durable TENG film. • Flame-retarding, transparent and flexible epoxy-based ion-gel films. • Transparent and flexible triboelectric nanogenerators (TENGs) producing an output voltage and current of ~150 V and ~45 μA from an external mechanical stimulus.