Abstract
The high melting point molten organic salts N -alkylpyridinium hexafluorophosphates have been used as thermoregulated supports. The influence of the structure of the molten organic salts on hydrosilylation reactions has been investigated and it was found that the alkyl chains attached to the pyridinium have an impact on the catalytic activities and selectivities. Additionally, by using this kind of thermoregulated catalyst support, the catalyst phase is liquid phase under the reaction conditions, whereas the catalyst supported by molten organic salt is solid phase at room temperature, therefore, it can be reused simply by decantation.
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