Abstract

Samples of sweet and dessert wines, Vin Santo (VSR) from Malvasia grapes, and Granello (GR) from Sauvignon grapes were collected and analyzed for the content of selected macro- and micro-nutrients (Na, K, Mg, Ca, Mn, Fe, Cu and Zn) and of Pb. GR wines had low levels for Fe, Cu and Zn, when compared to VSR and in particular Zn was two orders of magnitude lower. Methods to decrease the content of Zn and Cu in VSR, as well as those for reducing, at the same time, the concentrations of Ca, Mg and K in both VSR and GR, to avoid the formation of opalescence and depots of metal tartrates, were studied. Synthetic hydrogels containing l-histidine residue were tested. The overall relative lowering effects were by ca 4, 23, and 12% for K, Mg and Ca contents, and ca 6, 27 and 10%, for Mn, Cu and Zn contents, in GR wine samples. Commercial ion exchange resin Lanxess Lewatit L-207 and L-208 were then assayed, being legally allowed in the agro-food industry. The L-207 resin revealed great lowering effects on the concentrations of Mn, Cu and Zn, being 75, 91 and 97%, respectively, in VSR wines and 77, 76 and 92%, respectively, in GR wines. The content of Zn was reduced from 49.3 ± 1.2 mg/L in the original wine, down to 1.1 ± 0.1 mg/L, within 48 h soaking. The effects on the character of the dessert wines by the resin L-207 was also taken under control, measuring pH and color index. The color index changed by ca 15% and pH by ca 6% upon treatment of VSR wine with L-207 resins (48 h).

Highlights

  • Vin Santo (VSR) is a well known dessert wine produced and used mostly in Tuscany region (Italy) for several centuries, but even other regions in Italy contribute to the production of this beverage [1].the European Community regulation by the year 2005 admits the usage of the term for certain dessert wine from the Santorini island in Greece [2]

  • It is well known that pH higher than 3.8–4.0 negatively influence on the color and aroma, and decreases the chemical and microbiological stability of wines [3,4,5,6]. It is known, that wines at high pH cannot be corrected by addition of acids for several reasons: for example, the wine could already have a high tartaric acidity, and further addition of organic acid could allow the formation of potassium hydrogen tartrate (KHT) deposits, especially if the content of potassium is high

  • The contents of the alkali metals CNa, CK, CMg and CCa averaged 28.3 ± 0.3, 754 ± 17, 200 ± 6, and 60 ± 3 mg/L at plateau underwent a significant decrease with respect to the initial values (7th day for GR samples; Table 1)

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Summary

Introduction

Vin Santo (VSR) is a well known dessert wine produced and used mostly in Tuscany region (Italy) for several centuries, but even other regions in Italy contribute to the production of this beverage [1].the European Community regulation by the year 2005 admits the usage of the term for certain dessert wine from the Santorini island in Greece [2]. It is well known that pH higher than 3.8–4.0 negatively influence on the color and aroma, and decreases the chemical and microbiological stability of wines [3,4,5,6]. It is known, that wines at high pH cannot be corrected by addition of acids (i.e., tartaric acid, succinic acid) for several reasons: for example, the wine could already have a high tartaric acidity, and further addition of organic acid could allow the formation of potassium hydrogen tartrate (KHT) deposits, especially if the content of potassium is high. In the case of the common divinylbenzene family resins, the supporting skeleton is functionalized with groups having high affinity towards cations and anions

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