Abstract
An electrochemical technique has been employed to study the ionization of the iodine complexes of (C6H5)3As, (C6H5)3Sb, and pyridine. Several different ionization mechanisms are proposed depending on the chemical nature and concentration of the reactants. A new ionic complex, (C6H5)3MI22+ is postulated for the interaction of iodine with (C6H5)3As and (C6H5)3Sb at high iodine concentrations. Equilibrium constants have been calculated from the emf data for the various ionization steps. Key words: triphenylarsine, triphenylstibine, iodine, complex formation, ionization.
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