Abstract
The electrical conduction in sintered fluorocomplexes Li m MF 6, MAl, Ti was investigated by electrochemical methods. New electrolytic cells were designed to check the charge carrier in such materials and the ionic transport numbers were measured. Fluorocomplexes examined here showed the lithium ion conduction; the conductivities were 2×10 −4 and 6×10 −5 S cm −1 at 300°C for Li 2TiF 6 and Li 3AlF 6, respectively. Addition of different kinds of lithium fluorocomplex to introduce lattice defects (lithium ion vacancies or interstitial lithium ions) enhanced the electrical conductivity. A small electronic contribution to conduction was observed in Li 2TiF 6-based conductors.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
