Abstract

The travelling waves of the front type that are initiated in a system in which there is an ionic autocatalytic reaction, with a quadratic rate law, are considered when a constant current I is applied. These waves are seen to depend on both the current and the parameter δB, the ratio of diffusion coefficients of autocatalyst and substrate. For δB > 1 there is a transition from kinetic front waves to Kohlrausch electrophoretic fronts as I is varied. For δB < 1, both kinetic waves and Kohlrausch fronts are seen as well as an additional type of wave where a much enhanced reaction takes place.

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