Abstract
Ionenes are used as polymeric pseudostationary phases in capillary electrokinetic chromatography. These polymers are composed of charged ammonium moieties interconnected with aliphatic carbohydrate chains and/or aromatic rings within the molecule. The effect of the ionene structure and its concentration in the background electrolyte on migration and separation of analytes was examined. The investigated systems were shown to be suitable for the separation of uncharged analytes possessing hydrophobic or aromatic groups.
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