Abstract

The dielectric constant of aqueous MgCl2 solution has been determined in the frequency range 0.2 MHz to 20 GHz at 298 K using the dielectric relaxation spectroscopy method. The behavior is well described according to four Cole-Cole terms whose evolution with composition is analyzed. The static dielectric constant and relaxation times decreases with the increasing aqueous MgCl2 solution concentrations. Only one H-bonded water cluster with the aqueous MgCl2 solution relaxes is reported during the cutoff relaxation time. A distinct ion–water cooperative interaction is observed, and water molecules perturbed by ion contribution on dielectric constant beyond the first hydration shell are obtained.

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