Abstract
Electrochemical and NMR experiments with solutions of silver salts in mixtures of water—acetonitrile, water—dimethylsulphoxide, and methanol—dimethylsulphoxide have been compared and discussed in terms of ion solvation and solvent-solvent interactions. The solvation of aluminum(III) in mixtures of N,N-dimethylformamide, dimethylsulphoxide, and nitromethane depends also on solvent-solvent interactions, as 1H- and 27Al-NMR measurements show.
Published Version
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