Abstract
Ion-pair formation effects on the electroreduction of 21 carbonyl compounds were studied systematically in N,N-dimethylformamide (DMF). The degree of the shift of half-wave potentials due to ion-pair formation was observed in the order of p-quinones ρ α -diketones<aromatic ketones<σ-quinones. The thermodunamic properties of several ion associates were evaluated and their structures were discussed, together with the results of the column electrolysis ESR method.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
