Abstract
Electrical conductances of tetraalkylammonium iodides, R4NI (R = pentyl to heptyl) have been measured at 298.15 K in low-permittivity mixtures of 1,4-dioxane (ε = 2.21) and tetrahydrofuran (ε = 7.58). Minima in the conductometric curves (Λ versus √c) were observed for electrolyte concentrations dependent upon both the electrolyte and the binary solvent mixture. The conductance data have been analyzed by the Fuoss−Kraus theory of triple ions. A numerical evaluation of ion-pair and triple-ion formation constants (KP and KT) was made, and the results have been discussed in terms of a molecular scale model.
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