Ion-molecule charge exchange in Io's extended atmosphere: Velocity dependence

Abstract

The Io plasma torus is mostly composed of electrons and ions of O and S, singly and multiply-charged. These ions interact with the neutral species of Io's atmosphere (S, O, SO2 and SO) through symmetrical (e.g., O+ + O ⇒ O + O+) and asymmetrical (e.g., S+ + O ⇒ S + O+) charge exchange reactions. Moreover, molecular ions (SO2+, SO+) produced in Io's atmosphere by ionization or charge exchange are accelerated as they are picked up by the local plasma flow and eventually also charge exchange with the atmospheric neutrals (e.g., SO2+ + SO2 ⇒ SO2 + SO2+).Cross sections for many charge exchange reactions were estimated in Johnson and Strobel (1982) and McGrath and Johnson (1989) for ion speeds of 60 km/s appropriate for torus/neutral cloud interactions where the plasma is approximately at corotation in Io's reference frame. But close to Io, the flow velocity and ion temperature are drastically reduced (Vflow < 10 km/s and Tion < 50 eV) and greatly increased on its flanks (∼80 km/s and 400 eV). Thus, velocity-dependent charge exchange cross sections are critical for numerical simulations of the Io plasma/atmosphere interaction.We provide estimates of charge exchange cross sections of ions on molecular neutrals and of molecular ions on neutrals for the range of velocity [5–120] km/s representative of ion velocities at Io. We combine several methods valid at the low and higher velocities in this range: Two-state impact parameter approximation, quasi-thermal rate constant extrapolation, Langevin orbiting cross sections and scaling from experimental data. We describe these methods in details.Our estimates at 60 km/s are 2–3 times smaller or larger than previously published values, depending on the reaction. Most are generally large (∼60–90 Å2) at small velocities. We discuss the most important reactions relevant to Io's interaction and where improvements and experimental values are needed. We anticipate the effect of these velocity-dependent cross sections in numerical simulations of Io's interaction and show that some of these reactions are of critical importance regarding the plasma composition close to Io, the plasma supply to the torus and the neutral supply to Io's corona and to the giant neutral clouds that extend along Io's orbit.