Abstract
Characteristics of ion mixing in thin Ag-films deposited onto Si-substrates were studied using the Rutherford backscattering (RBS) technique. The mixing was induced by a 400 keV 40Ar + beam with a flux of 0.2 μA/cm 2 and fluences of up to 4×10 17 ions/cm 2. The concentration of Ag and Si atoms and their distributions in depth within the mixed region were determined. The RBS data indicate a clear broadening of the interfacial edges of Ag and Si distributions caused by atomic intermixing of the interface for doses above 7×10 16 ions/cm 2. The size of the intermixed region increases with increasing Ar fluence. Experimental findings also indicated that radiation-enhanced diffusion had not been totally eliminated. The mixing efficiency and diffusivity of Si and Ag were determined. Theoretical models were used to describe the mixing process. A comparison of our data with theory revealed that Ag diffuses in Si according to a local ‘thermal spike’ model. The above results when compared with our earlier studies of the Ag/Si system at a flux of 0.6 μA/cm 2 under otherwise similar conditions indicate that the mixing in this system is flux dependent.
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