Abstract
The kinetics of K+‐Na+ exchange in sodium borosilicate glasses containing 20 mol% Na2O were studied as a function of glass composition and exchange time and temperature. The distribution of K in the glass after exchange in molten KNO3 was determined using an electron microprobe. In those specimens which were not chemically attacked by the molten salt, the K profiles were consistent with Fickean behavior. The calculated interdiffusion coefficients varied with local composition in each specimen. This composition dependence and its variation with temperature could be fitted approximately to a mixed‐alkali model using the Nernst‐Planck relation for diffusive fluxes. However, some deviation from this behavior, presumably as a result of the generation of microscopic stresses around an exchange site, was observed. The dependence of the apparent activation energy, Ẽ, on the B/Si ratio was analogous to that of the activation energy for ionic conduction in these glasses: Ẽ decreased with increasing fraction of nonbridging oxygen. This result disagrees with the presumed behavior in sodium aluminosilicate glasses.
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