Abstract

Equations describing ion concentration profiles and electric charge in electrolyte solutions adjacent to an electrically charged cell membrane model in the electrochemical equilibrium state are developed and completely solved. The membrane system model consists of an infinitely large planar sheet of finite thickness separating two electrolyte solutions. Electric charges in the membrane model consist of planes of charge parallel to the surfaces of the planar sheet. The charge in solution adjacent to each surface of the membrane is due to differences in the total anion and cation concentrations in each solution. Expressions of concentration and charge are functions of the quantity and location of charge in the membrane, the various permittivities and thickness of the membrane, and the ionic compositions, permittivities, and temperature of the electrolyte solutions. The validity and relation of the model to real membranes are discussed.

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