Abstract
The ion chromatographic separation of methylmercury, ethylmercury and inorganic mercury as cysteine complexes was investigated. The chromatographic apparatus was interfaced with cold vapour atomic absorption spectrometry for detection using an on-line continuous flow cell coupled with a reduction system (sodium tetrahydroborate). The influence of the composition of the eluent (pH, ionic strength, cysteine concentration) and stripping gas flow-rate was investigated. The method was optimized by coupling an on-line preconcentration step. The detection limits, evaluated on 100.0-ml samples, were 2, 10 and 4 ng for Hg, CH3Hg and C2H5Hg, respectively. The method was applied to synthetic mixtures and natural samples (tap water) and furnished satisfactory results.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.