Abstract
Abstract The kinetic investigation for the iodo-ligand substitution of [Pd(pp3)I]+ (pp3 = tris(2-diphenylphosphinoethyl)phosphine) by trimethylphosphite in CDCl3 has been performed by 31p NMR spectroscopy. The trigonal-bipyramidal structure of the reactant and product has been confirmed by X-ray analysis and 31p NMR spectra. The associative mode in the activation process is first proposed for the trigonal-bipyramidal palladium(II) complexes.
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