Abstract
In comparison with the intensive attention paid on porous electron-conductive metal-organic frameworks (MOFs), regenerable and solution-processable porous conductive supramolecular self-assemblies constructed via non-covalent interactions are far less explored. Here, an array of discrete hexagonal nanotubes consisting of π-stacked columns is assembled. The nanotube is formed by the alternative column-stacking of a cylindrical capsule {[MnLCl(DMF)]·Cl·dnbn}6 and a macrocycle {dnbn}6 (DMF = N,N'-dimethylformamide, L = tris(2-naphthimidazolylmethyl)amine, and dnbn = 3,5-dinitrobenzonitrile). Electrical conductivity study revealed that iodine uptake leads to two orders conductivity enhancement.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
