Abstract
In the title compound, C9H11ITe·C27H33ITe2 or (Mes)TeI·(Mes2Te)TeI(Mes) (Mes is mesityl or 2,4,6-trimethylphenyl), a strong Te⋯I interaction of 3.3157 (9) A links the Te atom of an iodidomesityltellurium(II) moiety, (Mes)TeI, and an I atom of the iodidotrimesitylditellurium(II) unit, (Mes2Te)TeI(Mes). Further weak Te⋯I contacts of 4.0818 (9) A give rise to one-dimensional chains along the b axis in the crystal structure. An intramolecular C—H⋯π(arene) interaction is present in the (TeMes2)TeI(Mes) moiety, with a C⋯Cg distance of 3.497 (9) A and a C—H⋯Cg angle of 142° (where Cg is the centroid of a mesityl ring of the Mes2Te moiety).
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