InVO4/β-AgVO3 Nanocomposite as a Direct Z-Scheme Photocatalyst toward Efficient and Selective Visible-Light-Driven CO2 Reduction.

Abstract

Photocatalytic CO2 reduction to solar fuel is a promising route to alleviate the ever-growing energy crisis and global warming. Herein, to enhance photoconversion efficiency of CO2 reduction, a series of direct Z-scheme composites consisting of β-AgVO3 nanoribbons and InVO4 nanoparticles (InVO4/β-AgVO3) are prepared via a facile hydrothermal method and subsequent in situ growth process. The prepared InVO4/β-AgVO3 composites exhibit enhanced photocatalytic activity for reduction of CO2 to CO under visible-light illumination. A CO evolution rate of 12.61 μmol·g-1·h-1 is achieved over the optimized 20% In-Ag without any cocatalyst or sacrificial agent, which is 11 times larger than that yielded by pure InVO4 (1.12 μmol·g-1·h-1). Moreover, the CO selectivity is more than 93% over H2 production from the side reaction of H2O reduction. Significantly, based on the results of electron spin resonance (ESR) and in situ irradiated XPS tests, it is proposed that the synthesized InVO4/β-AgVO3 catalysts comply with the direct Z-scheme transfer mechanism. Significantly improved photocatalytic activities for selective CO2 reduction could be primarily ascribed to effective separation of photoinduced electron-hole pairs and enhanced reducibility of photoelectrons at the conduction band of InVO4. This work provides a new insight for constructing highly efficient photocatalytic CO2 reduction systems toward solar fuel generation.