Abstract
[60]Fullerene-fused lactones can be electrochemically reduced under controlled potential electrolysis (PCE) to generate the corresponding dianionic species. The generated dianionic [60]fullerene-fused lactones are then treated with acids and different electrophiles to afford the [60]fullerene-fused ketones, alkylated 1,2- and 1,4-adducts, and cyclic adducts with a medium or large ring.
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