Abstract

Single crystals of chlorine dioxide were grown in situ on a four-circle diffractometer, and the crystal structures were solved at five different temperatures (-75, -90, -110, -130, and -150 o C). At -150 o C, the crystal system, space group, unit cell parameters, and R factor are as follows: orthorhombic, Pbca, a=10.767 (12) A, b=6.654 (3) A, c=5.518 (1) A, V=395.29 (48) A 3 , Z=8, R=0.024. In the solid state, the ClO 2 molecules associate to form weakly bonded dimers which are «head to tail» with respect to one Cl-O bond

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