Investigations on proton conducting biopolymer membranes based on tamarind seed polysaccharide incorporated with ammonium thiocyanate

Abstract

Naturally available materials such as biopolymers and polysaccharides have gained much attention in the development of polymer electrolytes due to its biodegradability, film forming nature and non-toxicity. The proton conducting biopolymer membranes have been prepared by polysaccharides, tamarind seed polysaccharide (TSP) with different concentrations of ammonium thiocyanate (NH4SCN) as dopant. Distilled water has been used as a solvent and solution casting technique has been employed to prepare the biopolymer membranes. The prepared biopolymer membranes have been characterized by different techniques such as X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), AC-impedance spectroscopy and transference number measurement (TNM). From XRD results, the crystalline or amorphous nature of the biopolymer membranes with increasing salt concentration (NH4SCN) has been studied. The complex formation between the biopolymer-TSP and NH4SCN has been investigated by FTIR analysis. The glass transition temperature of the prepared biopolymer membranes has been found using DSC technique. The highest conductivity is 2.85×10−4Scm−1 for the composition of 1g TSP: 0.4g NH4SCN at ambient temperature, which has been obtained by AC-impedance spectroscopic studies. The conduction of ions within the biopolymer membrane has been confirmed by TNM. The primary proton battery has been constructed with the highest conducting membrane 1g TSP: 0.4g NH4SCN. Its open circuit voltage is 1.51V. The discharge characteristics of the battery for a load 1MΩ has been explained. The present investigation confirms that the NH4SCN doped TSP biopolymer membrane has got the essential properties required for the electrochemical device applications.