Investigations of the redox process of conducting poly(2-methyl-5-amino-1,4-naphthoquinone) (PMANQ) film: Interactions of quinone–amine in the polymer matrix

M.C Pham,S Hubert,B Piro,F Maurel,H Le Dao,H Takenouti

doi:10.1016/s0379-6779(03)00373-4

Investigations of the redox process of conducting poly(2-methyl-5-amino-1,4-naphthoquinone) (PMANQ) film: Interactions of quinone–amine in the polymer matrix

M.C Pham, S Hubert + Show 4 more

https://doi.org/10.1016/s0379-6779(03)00373-4

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Journal: Synthetic Metals	Publication Date: Jul 26, 2003
Citations: 12

Affiliation: Université Paris Cité, French National Centre for Scientific Research, Délégation Paris 7, Interfaces Traitements Organisation et Dynamique des Systèmes, Institut National de la Recherche Scientifique, Laboratoire de Physique de l'ENS

#Multiple Internal Reflection Fourier Transform Infrared Spectroscopy #Electrochemical Quartz Crystal Microbalance + Show 8 more

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Abstract

Poly(2-methyl-5-amino-1,4-naphthoquinone) (PMANQ) film is a new functionalized conducting polymer having two distinct redox systems. The polymer structure is of the polyaniline-type, bearing one methylquinone group per monomer unit. The redox mechanisms of PMANQ were investigated by in situ multiple internal reflection Fourier transform infrared spectroscopy (MIRFTIRS) and electrochemical quartz crystal microbalance (EQCM). It is shown that interactions occur between quinone and amine groups in the polymer chain.

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