Investigations of the Density and Solubility of Ammonium Perrhenate and Potassium Perrhenate Aqueous Solutions.

Abstract

Rhenium is largely used as an additive to nickel- and cobalt-based superalloys. Their resistance to temperature and corrosion makes them suitable for the production of turbines in civil and military aviation, safety valves in drilling platforms, and tools working at temperatures exceeding 1000 °C. The purity of commercial rhenium salts is highly important. Potassium, which is a particularly undesirable element, can be removed by recrystallization. Therefore, it is crucial to possess detailed knowledge concerning process parameters including the dissolved solid concentration and the resulting saturation temperature. This can be achieved using simple densimetric methods. Due to the fact that data concerning the physicochemical properties of ammonium perrhenate (APR) NH4ReO4 and potassium perrhenate (PPR) KReO4 are imprecise or unavailable in the scientific literature, the goal of this study is to present experimental data including the solubility and density of water solutions of both salts. In the experiments, a densimeter with a vibrating cell was used to precisely determine the densities. Although the investigated solutions did not fit into the earlier proposed mathematical model, some crucial conclusions could still be made based on the results.