Investigation on the thermal stability of nitroguanidine by TG/DSC-MS-FTIR and multivariate non-linear regression

Abstract

Thermal behavior of nitroguanidine (NQ) has been investigated by TG/DSC-MS-FTIR simultaneous analysis performed under both isothermal and nonisothermal conditions. The isothermal test at 230 °C indicated that the release of gas products can be divided into several stages. The processing of the non-isothermal data, namely 5, 10, 15, and 20 K/min, was performed by using Netzsch Thermokinetics. The dependence of the activation energy evaluated by Friedman’s isoconversional method on the conversion degree shows that the investigated process is complex one, and can be divided into three parts. The mechanism of the process and the corresponding kinetic parameters were determined by Multivariate Non-linear Regression Program. The kinetic results was used to simulate the thermal decomposition of NQ under isothermal condition at 210 °C. The simulated curve is in agreement with the tested curve. The obtained results were also used for prediction of the thermal lifetime of NQ corresponding to a certain temperature.