Investigation on the Molecular Shear-Induced Organization in a Molecularly Thin Film of N-hexadecane

Abstract

The frictional properties of a thin hexadecane film confined between two atomically smooth surfaces of mica were studied using the surface forces apparatus equipped with a 3D actuator–sensor attachment specially designed to investigate static and dynamic forces in three orthogonal directions simultaneously. The use of this attachment allows the relative alignment of the reciprocal sliding motion to be changed by an angle of 90° while maintaining the film under the same confinement conditions. The effects of the commensurability of the confining mica surfaces as well as the relative sliding direction on the frictional behavior of the hexadecane film were determined for different temperatures (18–29 °C) and sliding velocities (4 nm/s to 4 μm/s). The confined hexadecane film exhibited smooth sliding friction whose amplitude increased with the commensuration of the surfaces. A progressive evolution in the kinetic friction force toward a steady-state value was observed over reciprocal sliding motion for given experimental conditions of applied load, sliding velocity and environmental temperature. This friction evolution shows to be dependent on the sliding history of the film and could result from a partial molecular ordering, occurring during shear.