Investigation on the interlayer intercalation inhibition mechanism of polyamines with different adsorption functional groups on montmorillonite: Experiment and density functional theory simulation

Abstract

Water-based drilling fluids (WBDFs) are gaining popularity as they exhibit comparable inhibitory properties to oil-based drilling fluids, making them an ideal choice for drilling horizontal shale gas wells. This study focuses on understanding the intercalation inhibition mechanism of various inhibitors, namely 1,6-hexane diamine (HDA), N,N′-dimethyl-1,6-hexane diamine (DHDA), N,N,N′,N′-tetramethyl-1,6-hexane diamine (THDA), and hexamethyl diammonium chloride (HDC), each possessing different functional groups. The interaction and performance of these inhibitors on the swelling of montmorillonite (Mt) were investigated through a combination of experimental techniques containing X-ray diffraction, thermogravimetric analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, and density functional theory simulation. Results reveal that at a low dosage of 0.7 CEC (cation exchange capacity), the wet Mt-HAD, Mt-DHDA, Mt-THDA, and Mt-HDC compounds exhibit basal spacing of 1.30 nm, 1.33 nm, 1.34 nm, and 1.42 nm, respectively. The basal spacing remains unchanged when a higher dosage of 3.0 CEC is added. Comparatively, the basal spacing of dry Mt-inhibitor compounds is slightly reduced. This suggests that the addition of a smaller amount of inhibitor also demonstrates excellent inhibitory performance. Thermogravimetric and differential thermogravimetric analysis of Mt-inhibitor hybrid structure indicate that Mt-HDA compounds exhibit both low and high-temperature peaks, while Mt-DHDA, Mt-THDA, and Mt-HDC compounds only show a low-temperature peak. This indicates that while HDA partially inhibits surface hydration of Mt, DHDA, THDA, and HDC effectively inhibits surface hydration of Mt. Additionally, the microscopic mechanism of inhibitor adsorption on the Mt was explored using density functional theory simulation. HDC adsorption energy on Mt significantly increased relative to DHDA, THDA, and HDA. This indicates that inhibitors featuring quaternary ammonium functional groups exhibited superior inhibitory performance. As a result, inhibitors with quaternary ammonium functional groups hold promise as potential shale inhibitors for WBDFs.