Abstract
Potentiometric and UV spectroscopic measurements have been carried out to determine the stability constants for the complexation of the MoO42– ion with d-(−)-quinic acid {(1R,3R,4S,5R)-(−)-1,3,4,5-tetrahydroxycyclohexane-1-carboxylic acid} in sodium chloride aqueous solutions for ionic strengths between (0.10 to 1.00) mol·L–1 of sodium chloride at T = 298 K. The Job method of continuous variations was applied for the determination of the metal-to-ligand ratio which was 1:1 at pH = 6.50. Extended Debye–Huckel type (EDH), specific ion interaction theory (SIT), and parabolic equations were investigated to derive the necessary ionic strength dependence parameters, and the results were justified.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have