Abstract

An experimental research was carried out on formation characteristics of aerosol particles during the Wet Flue Gas Desulfurization (WFGD) process with different ammonia-based desulfurizers. Three desulfurizers of aqueous ammonia, ammonium sulfate, and ammonium sulfite were compared and influences of desulfurization operating conditions were investigated. The results revealed that numerous aerosol particles were produced during the desulfurization process for all three desulfurizers. In terms of the quantity of aerosol particles produced, the aqueous ammonia and ammonium sulfite took the first and second place, respectively. Ammonium sulfate produced the least aerosol particles, with submicron sizes for most cases. For all three desulfurizers, the production rate of aerosol particles increased with increasing liquid-to-gas ratio, pH value as well as the desulfurization liquid temperature; a higher concentration of SO2 in the flue gas resulted in more aerosol particles being generated at a lower pH value of...

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