Abstract
Zirconia coatings were formed on zirconium-niobium alloy (1 % Nb) by plasma electrolytic oxidation (PEO) in silicate-hypophosphite electrolyte with Y2O3 nanopowder additives. The structure, elemental composition and layer-by-layer phase composition of the PEO coatings were investigated using methods of scanning electron microscopy (SEM), X-ray microanalysis, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS). PEO coatings formed in an electrolyte with 6 g/L Y2O3 nanoparticles additive contain predominantly tetragonal t-ZrO2 phase and have the superficial layer mainly consisting of electrolyte components and their compounds, including yttria and yttrium silicate. Moreover, stabilization of the t-ZrO2 phase in the PEO coating leads to increase its hardness up to 4.6 GPa.
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